Palladium diarsenide
Identifiers
Properties
PdAs2
Molar mass 256.26
Density 7.9 g·cm−3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Palladium diarsenide is an inorganic compound with the chemical formula PdAs2. It is one of the arsenides of palladium.

Preparation

Palladium diarsenide can be obtained by the reaction of palladium and arsenic:[1]

Pd + 2 As → PdAs2

In the reaction of palladium and gallium arsenide (350~800 °C), palladium disarsenide will also be formed:[2]

3 Pd + 2 GaAs → 2 PdGa + PdAs2

It is a cubic crystal with a = 5.983 Å.[3]

References

  1. Ch.J Raub, G.W Webb (Jun 1963). "An investigation of the phase-diagram palladium-arsenic in connection with superconductivity". Journal of the Less Common Metals. 5 (3): 271–277. doi:10.1016/0022-5088(63)90032-8. Archived from the original on 2018-06-05. Retrieved 2021-12-10.
  2. Y. C. Zhao, Z. Q. Wu (1991-01-28). "Reactions in Pd/GaAs(001) contacts at 7×10 8 Pa pressure". Applied Physics Letters. 58 (4): 349–351. doi:10.1063/1.104630. ISSN 0003-6951. Retrieved 2021-12-10.
  3. G. S. Saini, L. D. Calvert, R. D. Heyding, J. B. Taylor (1964-03-01). "ARSENIDES OF THE TRANSITION METALS: VII. THE PALLADIUM–ARSENIC SYSTEM". Canadian Journal of Chemistry. 42 (3): 620–629. doi:10.1139/v64-091. ISSN 0008-4042. Retrieved 2021-12-10.{{cite journal}}: CS1 maint: multiple names: authors list (link)
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