A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite and nitrate anions (NO3− and NO2−). They are mixed-anion compounds, and they are mixed-valence compounds. Some have third anions. Many nitrite nitrate compounds are coordination complexes of cobalt. Such a substance was discovered by Wolcott Gibbs and Frederick Genth in 1857.

Production

Mercuric nitrate and potassium nitrate in water solution produce the potassium mercuric compound K3[Hg(NO2)4]NO3.[1]

Properties

On heating, nitrate nitrites lose NO2 and NO and yield metal oxides.

Other compounds having an element in two different anion states include the sulfate sulfites, the phosphate phosphites, arsenate arsenites and the selenate selenites.

List

name formula ratio

NO3:NO2

 mw system space group unit cell Å volume density properties references
[Cr(NH3)5(NO2)] ·(NO3)2 [2]
trans-dinitrotetraamminecobalt(III) nitrate monohydrate [Co(NO2)2(NH3)4]NO3•H2O 1:2 orthorhombic P212121 a=10.02, b=6.02, c=16.84, Z=4 1.84 [3]
cis-dinitrotetraamminecobalt(III) nitrate [Co(NO2)2(NH3)4]NO3 1:2 orthorhombic P212121 a=12.19, b=7.18, c=10.92, Z=4 1.95 [4]
[cis-β-Co(trien)(NO2)2]NO3 1:2 monoclinic P21/n a = 7.604, b = 13.019, c = 14.472, β = 98.13°, Z = 4 1418.26 1.682 racemate [5]
[cis-α-Co(tren)(NO2)2]NO3•13H2O 1:2 P21/c [6]
trans-Co[(en2)(NO2)2]NO3 1:2 [7]
trans-[Co(2,3,2-tet)(NO2)2]NO3 1:2 373.21 P21/n a=8.490, b=8.884, c=18.580 and β=95.08°;, Z=4 1395.89 1.776 [8]
trans-[Co(2,3,2-tet)(NO2)2]NO3 373.21 Pn a=6.493, b=11.731, c=9.325 β=100.13°; M.W.=373.21, Z=2)= 699.21 1.773 [8]
cis-[Co(Hao)2(NO2)2]NO3 (Hao = 3-amino-3-methyl-2-butanone oxime) monoclinic P21/n a= 8.1 60, b= 17.250, c= 13.745, β= 104.77° [9]
[Co(pic)2(NO2)2]NO3.½H2O pic=2-picolylamine [10]
cis-[Co(phen)2(NO2)2]NO3 · 2 H2O phen=1,10-phenanthroline [11]
Sparteine copper(II) nitrate nitrite Cu(C15H26N2)(NO3)(NO2) 1:1 green [12]
trans-diammine-cis-dinitratonitronitrosyl ruthenium(II) RuNO(NH3)2(NO3)2(NO2)
bis(nitrotriamminepalladium(II)) tetraamminepalladium(II) tetranitrate [Pd(NO2)(NH3)3]2[Pd(NH3)4](NO3)4 4:1 829.20 tetragonal I42m a=7.637 c=21.610 Z=2 2.18 bright yellow [13]
bis(1,10-Phenanthroline)-(nitroso-O)-(nitrato-O,O')-cadmium(ii) Cd(phen)2(NO3)(NO2) monoclinic P21/c a 6.872 b 9.690 c 20.852 β 93.59° [14]
catena-((μ2-Nitroso-O,O')-aqua-(nitrato-O,O')-(1,10-phenanthroline)-cadmium(ii)) [Cd(phen)(NO3)(NO2)(H2O)]n monoclinic Cc a 11.703Å b 15.242 c 13.451 β 106.321° [14]
[NO2(NH3)2Pt(C5H4NO)2Pt(NH3)2NO2](NO3)2.H2O yellow [15]
K3[Hg(NO2)4]NO3 1:4 orthorhombic Pnma a=12.12 b=10.58 c=9.28 Z=4 3.14 pale yellow [1]
Pb2(NO2)(NO3)(SeO3) 1:1 orthorhombic Pmn21 a=5.529, b=10.357, c=6.811, Z=2 390 colourless [16]
K2Pb(NO2)3(NO3) 1:3 503.4 orthorhombic Pbca a = 6.766, b = 11.999, c = 26.61, Z = 8 2160 3.095 yellow orange [17]
[Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O 1:4 orthorhombic Pbca a = 8.9414, b = 14.5330, c = 24.9383, Z = 8 3240.6

References

  1. 1 2 Hall, D.; Holland, R.V. (January 1969). "The crystal structure of K3[Hg(NO2)4]NO3". Inorganica Chimica Acta. 3: 235–238. doi:10.1016/S0020-1693(00)92486-1.
  2. ↑ Shepard, Whiting N.; Forster, Leslie S. (1971). "The2 E?4 A 2 transition in tetragonal Cr3+ complexes". Theoretica Chimica Acta. 20 (2): 135–142. doi:10.1007/BF00569260. ISSN 0040-5744. S2CID 95534463.
  3. ↑ Oonishi, Isao; Muto, Fumio; Komiyama, Yoshimichi (October 1969). "The Molecular and Crystal Structure of trans -Dinitrotetramminecobalt(III) Nitrate Monohydrate". Bulletin of the Chemical Society of Japan. 42 (10): 2791–2796. doi:10.1246/bcsj.42.2791. ISSN 0009-2673.
  4. ↑ Oonishi, Isao; Fujimaki, Hiroto; Muto, Fumio; Komiyama, Yoshimichi (March 1970). "The Crystal Structure of cis -Dinitrotetraamminecobalt (III) Nitrate". Bulletin of the Chemical Society of Japan. 43 (3): 733–739. doi:10.1246/bcsj.43.733. ISSN 0009-2673.
  5. ↑ Bernal, Ivan; Cetrullo, James (October 1986). "The phenomenon of conglomerate crystallization. VII. Clavic dissymmetry in coordination compounds.V. An investigation of the crystallization behavior of [cis-β-Co(triethylenetetramine)(NO2)2]X (X = I, NO3) and the crystal structure of racemic [cis-β-Co(trien)(NO2)2]NO3". Inorganica Chimica Acta. 120 (2): 109–117. doi:10.1016/S0020-1693(00)86096-X.
  6. ↑ Bernal, Ivan; Cetrullo, James; Myrczek, Jozef (October 1993). "The phenomenon of conglomerate crystallization Part XXXI. The crystallization behavior of [cis-Co(en)2(NO2)2Br and of : counter-ion effects on crystallization pathway of racemate solutions". Materials Chemistry and Physics. 35 (3–4): 290–300. doi:10.1016/0254-0584(93)90145-C.
  7. ↑ Charpeutier, T.; Virlet, J. (October 1998). "Triple quantum MQMAS spectroscopy of (I=7/2) in Na3Co(NO2)6 and trans-Co[(en2)(NO2)2]NO3 interplay between the quadrupole coupling and anisotropic shielding tensors". Solid State Nuclear Magnetic Resonance. 12 (4): 227–242. doi:10.1016/S0926-2040(98)00051-4. PMID 9800268.
  8. 1 2 Bernal, Ivan; Somoza, Fernando; Chen, Ya-Chen; Massoud, Salah S. (April 1997). "The Phenomenon of Conglomerate Crystallization. Part 48. Two Polymorphs of Racemic Trans-[Co(2,3,2-Tet) (No2)2]No3(I and Ii)". Journal of Coordination Chemistry. 41 (3): 233–247. doi:10.1080/00958979708023574. ISSN 0095-8972.
  9. ↑ Murray, Don E.; Schlemper, Elmer O.; Siripaisarnpipat, Sutatip; Murmann, R. Kent (1986). "A structural and isotopic NO 2 – exchange rate comparison of trans-[Co(ao–H–ao)(NO 2 ) 2 ] and cis-[Co(Hao) 2 (NO 2 ) 2 ]NO 3". J. Chem. Soc., Dalton Trans. (9): 1759–1765. doi:10.1039/DT9860001759. ISSN 0300-9246.
  10. ↑ Sutton, Gj (1960). "Some Studies in Inorganic Complexes. VIII. Cobalt(II) and Cobalt(III) with 2-Picolylamine". Australian Journal of Chemistry. 13 (4): 473. doi:10.1071/CH9600473. ISSN 0004-9425.
  11. ↑ Ghaschghaie, Natascha (2010). "HETEROLEPTISCHE COBALT(III)-CHELATKOMPLEXE MIT BIOLIGANDEN" (PDF).
  12. ↑ Lee, Yong-Min; Kim, Yong-Kyu; Jung, Hee-Cheul; Kim, Young-Inn; Choi, Sung-Nak (2002-03-20). "Copper(II) Oxyanion Complexes Derived from Sparteine Copper(II) Dinitrate: Synthesis and Characterization of 4- and 5-Coordinate Copper(II) Complexes". Bulletin of the Korean Chemical Society. 23 (3): 404–412. doi:10.5012/BKCS.2002.23.3.404.
  13. ↑ Boer, F. Peter; Carter, Virginia B.; Turley, June W. (April 1971). "Single-crystal x-ray and Raman studies of bis(nitrotriamminepalladium(II)) tetraamminepalladium(II) tetranitrate". Inorganic Chemistry. 10 (4): 651–661. doi:10.1021/ic50098a001. ISSN 0020-1669.
  14. 1 2 Fan, Ruiqing; Zhang, Yanjiao; Yin, Yanbin; Su, Qing; Yang, Yulin; Hasi, Wuliji (June 2009). "Syntheses, structures, and luminescent properties of cadmium (II) complexes: 3D supramolecular [Cd(phen)(NO3)(NO2)(H2O)]n and Cd(phen)2(NO3)(NO2) constructed by π–π stacking interactions". Synthetic Metals. 159 (11): 1106–1111. doi:10.1016/j.synthmet.2009.04.007.
  15. ↑ Hollis, L. Steven; Lippard, Stephen J. (May 1982). "Effect of axial ligands on the platinum-platinum bond in binuclear .alpha.-pyridonate-bridged platinum(III) complexes. Structures of [X(NH3)2Pt(C5H4NO)2Pt(NH3)2X](NO3)2.H2O, X = NO3, NO2". Inorganic Chemistry. 21 (5): 2116–2117. doi:10.1021/ic00135a087. ISSN 0020-1669.
  16. ↑ Effenberger, Herta (February 1987). "Darstellung und Kristallstruktur von Pb2(NO2)(NO3)(SeO3)". Monatshefte für Chemie. 118 (2): 211–216. doi:10.1007/BF00810054. S2CID 101945551.
  17. ↑ Nardelli, Mario; Pelizzi, Giancarlo (January 1980). "Crystal structure of K2Pb(NO2)3(NO3)·H2O". Inorganica Chimica Acta. 38: 15–19. doi:10.1016/S0020-1693(00)91928-5.
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