Neodymium(III) acetylacetonate
Names
Other names
Neodymium acetylacetonate, Tris(acetylacetonato)neodymium
Identifiers
3D model (JSmol)
  • InChI=1S/3C5H7O2.Nd/c3*1-4(6)3-5(2)7;/h3*3H,1-2H3;/q3*-1;+3
    Key: AZTDRGMPTCCVFW-UHFFFAOYSA-N
  • CC(=O)[CH-]C(=O)C.CC(=O)[CH-]C(=O)C.CC(=O)[CH-]C(=O)C.[Nd+3]
Properties
C15H25NdO8
Molar mass 477.599 g·mol−1
Appearance White powder[1]
Melting point 150 °C (302 °F; 423 K)[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Neodymium(III) acetylacetonate is a coordination compound of neodymium and acetylacetone, with the chemical formula Nd(O2C5H7)3(H2O)2, although some sources ignore the aquo ligands.[2] It commonly occurs as a white powder.[1] Its instablility constants (logYn) are 2.89, 4.15 and 5.26 (corresponding to n = 1, 2, 3).[3] Its dihydrate reacts with carbonyl rhenium complex Re(CO)3X(4,4'-bipy) (X=Cl, Br) to obtain Re(CO)3X(4,4'-bipy)Nd(acac)3.[4]

Preparation

Neodymium(III) acetylacetonate can be obtained by reacting a lanthanum alkoxide with acetylacetone,[5] or by electrolysis of neodymium in acetylacetone.[6]

References

  1. 1 2 3 Pierson, H.O. (1999). Handbook of Chemical Vapor Deposition: Principles, Technology and Applications. Materials Science and Process Technology. Elsevier Science. p. 92. ISBN 978-0-8155-1743-6. Archived from the original on 2021-10-17. Retrieved 2021-09-16.
  2. ↑ Aslanov, L. A.; Porai-Koshits, M. A.; Dekaprilevich, M. O. (1971). "Crystal structure of neodymium trisacetylacetonate dihydrate". Journal of Structural Chemistry. 12 (3): 431–434. doi:10.1007/BF00744630. S2CID 96397811.
  3. ↑ N.K. Dutt; P. Banyopadhyay (May 1964). "Chemistry of the lanthanons—XIII". Journal of Inorganic and Nuclear Chemistry. 26 (5): 729–736. doi:10.1016/0022-1902(64)80316-X. Archived from the original on 2018-06-24. Retrieved 2022-07-02.
  4. ↑ Shapoval, A. N.; Bobukhov, D. V.; Rusakova, N. V.; Shtemenko, A. V.; Snurnikova, O. V.; Korovin, Yu. V. Synthesis and spectral-luminescent properties of mono- (Re+) and heteronuclear (Re+-Ln3+) tricarbonyl-halo complexes{{Country data {{{1}}} | flaglink/core | variant = | size = | name = | altlink = national rugby union team | altvar = rugby union}}. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2007. 73 (9-10): 34-36. ISSN 0041-6045.
  5. ↑ Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates{{Country data {{{1}}} | flaglink/core | variant = | size = | name = | altlink = national rugby union team | altvar = rugby union}}. Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.
  6. ↑ Panyushkin, V. T.; Frolov, V. Yu.; Zelenov, V. I. Electrochemical synthesis of rare-earth metal acetylacetonates. Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii), 2001. 71 (8): 1318.
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