Rivero is a surname. Notable people with the surname include:
- Andrés Rivero Agüero (1905 – 1996), Cuban politician and prime minister
- Ángel Rivero Méndez (1856 – 1930), Puerto Rican soldier, writer, journalist and a businessman
- Armando Rivero (born 1988), Cuban baseball player
- Bernardo Rivero (1889 – 1965), Peruvian painter
- Calu Rivero (born 1987), Argentine model and actress
- Carlos Rivero (disambiguation)
- Claudia Rivera (born 1986), Peruvian badminton player
- Claudio Rivero (born 1985), Uruguayan footballer
- Cristian Rivero (born 1978), Peruvian television host and actor
- Dante Rivero (born 1946), Filipino actor
- Diego Rivero (born 1981), Argentine football midfielder
- Diosbert Rivero (born 2000), Venezuelan footballer
- Edmundo Rivero (1911 - 1986), Argentine musician
- Felipe Rivero (born 1991), Venezuelan professional baseball pitcher
- Gabriela Rivero (born 1964), Mexican actress and singer
- Horacio Rivero, Jr. (1910 – 2000), the first Puerto Rican and Hispanic four-star Admiral in the U.S. Navy
- Ignacio Rivero (born 1992), Uruguayan footballer
- Inés Rivero (born 1975), Argentinian model
- Jasiel Rivero (born 1993), Cuban basketball player for Maccabi Tel Aviv in the Israeli Basketball Premier League
- Jennifer Ramírez Rivero (1978–2018), Venezuelan model and businesswoman
- Jorge Rivero (born 1938), Mexican actor
- José Rivero (born 1955), Spanish professional golfer
- José Ignacio Rivero (1920 – 2011), Cuban exile and journalist
- Juan A. Rivero (1923 – 2014), Puerto Rican biologist
- Juncal Rivero (born 1966), Spanish beauty queen, model and actress
- Lovely Rivero (born 1969), Filipino actress
- Martín Rivero (born 1989), Argentine footballer
- Mirtha Rivero (born 1956), Venezuelan journalist and writer.
- Octavio Rivero (born 1992), Uruguayan footballer
- Paulino Rivero (born 1952), Spanish politician
- Quique Rivero (born 1992), Spanish footballer
- Ramón Rivero (1909 – 1956), Puerto Rican comedian, actor, and composer
- Raúl Rivero (1945 – 2021), Cuban poet, journalist, and dissident
- Ricci Rivero (born 1998), Filipino basketball player
- Rolando Rivero (born 1944), Mexican politician
- Ronald Rivero (born 1980), Bolivian footballer
- Sebastian Rivero (born 1998), Venezuelan baseball player
- Toni Rivero (born 1988), taekwondo Olympian from the Philippines
- Viviana Rivero (born 1966), Argentine writer
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