Kazimierz Fajans
Kazimierz Fajans
Born(1887-05-27)27 May 1887
Warsaw, Poland
Died18 May 1975(1975-05-18) (aged 87)
Ann Arbor, Michigan, United States
Known for
Scientific career
InstitutionsUniversity of Michigan
University of Manchester
Doctoral studentsTheodore H. Berlin

Kazimierz Fajans (Kasimir Fajans in many American publications; 27 May 1887 – 18 May 1975) was a Polish American physical chemist of Polish-Jewish origin, a pioneer in the science of radioactivity and the co-discoverer of chemical element protactinium.

Education and career

Fajans was born May 27, 1887, in Warsaw, Congress Poland, to a family of Jewish background.[1] After he had completed secondary school in Warsaw (1904), he studied chemistry in Germany, first at the University in Leipzig, and then in Heidelberg and Zürich. In 1909 he was awarded his PhD for research into the stereoselective synthesis of chiral compounds.

In 1910 Fajans took a job at the laboratory of Ernest Rutherford in Manchester, where the nucleus was discovered. He then returned to Germany, where he became an assistant and subsequently assistant professor at the Technical University of Karlsruhe, researching radioactivity. In 1917 he headed the Faculty of Physical Chemistry at Munich University, and in 1932 became the Head of the Institute of Physical Chemistry established by the Rockefeller Foundation. In 1935 he left Germany due to escalating Nazi persecution. He stayed for a while in Cambridge and then moved to the University of Michigan where he worked until his demise. In 1959 he became an honorary member of the Polish Chemical Society.[2]

Fajans retired at age of seventy but never stopped working. He died May 18, 1975, in Ann Arbor, Michigan.

Scientific work

Fajans at the Bunsen Congress, Munich, 1928

Fajans worked with Henry G. Moseley at the laboratory of Ernest Rutherford researching properties of the radioactive rows of the periodic table. He identified the half-lives of the uranium-actinium row and thorium nuclides. He discovered the phenomenon of the electrochemical branching of the radioactive rows. Afterwards Fajans worked on the electrochemical properties of elements as a result of the radioactive changes, and he formulated the law of the radioactive shifts which was later named the radioactive displacement law of Fajans and Soddy (Frederick Soddy received the Nobel Prize in chemistry in 1921 for his isotopic research). In 1913, together with Oswald Helmuth Göhring, he discovered the first radionuclide of a new element, which was later named protactinium.[3] Fajans and Otto Hahn discovered the formula that defined the conditions of precipitation and absorption of radioactive substances. It is very significant for separation and purification of radioactive substances found in the smallest number.

In 1919, Fajans began researching the structure of crystals by thermochemical and refractometric methods. The co-relation of Born, Fajans and Haber is a basic thermochemical rule. On the basis of his research data Fajans formulated the essential relationships concerning chemical bond strength and deformation of ions and particles, such as heat of ion hydration, refractive index and the heat of sublimation. In 1923 he formulated Fajans' rules of inorganic chemistry, which are used to predict whether a chemical bond will be covalent or ionic.

In the United States he researched nuclear reactions using a cyclotron and discovered a radioactive lead isotope with Voigt, and a new rhenium isotope with Sullivan. He developed the quantum theory which explained chemical bonding through electrostatic impacts between quanta and nuclear cores. He was a member of the Polish Institute of Arts and Sciences in America and of many societies and academies.

Bibliography

  • 1913 - Radioactive Transformations and the Periodic System of the Elements
  • 1941 - Artificial radioactive isotopes of Thallium, Lead and Bismuth
  • 1947 - Application of the resonance theory to the structure of the water molecule
  • 1948 - Electronic structure of molecules

See also

References

  1. ↑ The Jews in Polish culture, Aleksander Hertz, Northwestern University Press, 1988, page 236
  2. ↑ "President of honour and honorary members of PTChem". Retrieved 23 February 2020.
  3. ↑ Fajans, K.; Morris, D. F. C. (1973). "Discovery and Naming of the Isotopes of Element 91" (PDF). Nature. 244 (5412): 137–138. doi:10.1038/244137a0.
  • "Kasimir Fajans". Journal of Nuclear Medicine. 7 (5): 402–404. May 1966. PMID 5328478.

Further reading

  • Hurwic, Józef (2000). Kasimir Fajans : (1887–1975) : Lebensbild eines Wissenschaftlers (in German). Berlin. ISBN 978-3-928577-37-3.{{cite book}}: CS1 maint: location missing publisher (link)
  • Hurwic, Józef (1987). "Reception of Kasimir Fajans's quanticule theory of the chemical bond: A tragedy of a scientist". Journal of Chemical Education. 64 (2): 122. Bibcode:1987JChEd..64..122H. doi:10.1021/ed064p122. OCLC 4666664486.
  • Hurwic, Józef. "Badania Kazimierza Fajansa w dziedzinie promieniotwórczości i izotopii". Kwartalnik Historii Nauki I Techniki / Kvartal'nyj Zurnal Istorii Nauki I Techniki = Quarterly Journal of the History of Science and Technology = Revue Trimestrielle d'Histoire de la Science et de la Technique (in Polish). ISSN 0023-589X. OCLC 13055784.
  • Dunn, Thomas M. (19 February 1976). "Kasimir Fajans". Nature. 259 (611): 611. Bibcode:1976Natur.259..611D. doi:10.1038/259611a0.
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