Egil Andersen Hylleraas
Born(1898-05-15)May 15, 1898
Engerdal, Norway
DiedOctober 28, 1965(1965-10-28) (aged 67)
NationalityNorwegian
Alma materUniversity of Oslo
Known forHylleraas co-ordinates
Hylleraas CI
Scientific career
FieldsTheoretical Physics
InstitutionsChristian Michelson Institute, Bergen
University of Oslo

Egil Andersen Hylleraas (May 15, 1898 – October 28, 1965) was a Norwegian theoretical physicist known for creating a method for predicting the ground state energy of two-electron atoms and trial wave functions for many-electron atoms.

Early life and education

Hylleraas was the son of Ole Andersen, a teacher in the mountain village of Engerdal, located in southern Norway. Hylleraas was the youngest of eleven children. He dropped out of school at a young age but later resumed his education at 17 by attending high school after moving to Oslo. He would later attend the University of Oslo and become a teacher. Hylleraas started research on the double refraction of light after reading a book by Max Born regarding crystal lattices. His paper earned him a fellowship from the International Education Board. From 1926 to 1928, he worked with Max Born at the University of Göttingen.

The Golden Age of Atomic Physics

In his journal Reminiscences,[1] Hylleraas referred to 1925–1930 as the Golden Age of atomic physics. It was when Bohr's theory of the atom was replaced by the new theory of quantum mechanics. By 1926, the one-electron hydrogen had been solved, and Werner Heisenberg had formulated the two-electron helium problem quantum mechanically. A simple first-order perturbation treatment still yielded considerably increased ionization potential for error with experimental measurement.[2] Max Born considered it crucial for quantum mechanics to provide a result in better agreement with experiments.

When Hylleraas arrived at Göttingen, he learned that Max Born had abandoned crystallography. He continued Max Born's work on crystals independently. Still, he was assigned to work on the helium problem when Bohr's student became ill. Hylleraas modified the first attempt in two ways: he replaced the incomplete bound state hydrogenic functions with the complete Laguerre functions. He reduced the number of coordinates from 6 to 3, namely the distances of the two electrons from the nucleus and the angle between the position vectors of the two electrons. He obtained results in much better agreement with the experiments with a mechanical desk calculator. The result was well received, but the discrepancy of 0.12 eV continued to bother him. A breakthrough was achieved in 1928 when Hylleraas realized the angle coordinate needed to be replaced by the distance between the two electrons. With only three terms in the wave function expansion, the error had been reduced to 0.03 eV, with six terms to 0.01 eV. His work was quickly applied to other two-electron atoms and the hydrogen molecule.

Hylleraas was one of the founding fathers of CERN and represented Norway at the European Council for Nuclear Research [3], which later led to the organization's establishment.

Awards

Selected publications

  • Hylleraas, Egil A. (1928). "Über den Grundzustand des Heliumatoms". Zeitschrift für Physik. 48 (7–8): 469–494. Bibcode:1928ZPhy...48..469H. doi:10.1007/BF01340013. S2CID 121512045.
  • Hylleraas, Egil A. (1929). "Neue Berechnung der Energie des Heliums im Grundzustande, sowie des tiefsten Terms von Ortho-Helium". Zeitschrift für Physik. 54 (5–6): 347–366. Bibcode:1929ZPhy...54..347H. doi:10.1007/BF01375457. S2CID 119898248. (over 1830 citations)
  • Hylleraas, Egil A. (1930). "Über den Grundterm der Zweielektronenprobleme von H–, He, Li+, Be++ usw". Zeitschrift für Physik. 65 (3–4): 209–225. Bibcode:1930ZPhy...65..209H. doi:10.1007/BF01397032. S2CID 122152260.
  • Hylleraas, Egil A.; Undheim, Bjarne (1930). "Numerische Berechnung der 2S-Terme von Ortho- und Par-Helium". Zeitschrift für Physik. 65 (11–12): 759–772. Bibcode:1930ZPhy...65..759H. doi:10.1007/BF01397263. S2CID 121637176.
  • Hylleraas, Egil A. (1931). "Über die Elektronenterme des Wasserstoffmoleküls". Zeitschrift für Physik. 71 (11–12): 739–763. Bibcode:1931ZPhy...71..739H. doi:10.1007/BF01344443. S2CID 121844820.
  • Hylleraas, Egil A.; Ore, Aadne (1947). "Binding Energy of the Positronium Molecule". Physical Review. 71 (8): 493–496. Bibcode:1947PhRv...71..493H. doi:10.1103/PhysRev.71.493.
  • Hylleraas, Egil A. (1963). "On the inversion of eigenvalue problems". Annals of Physics. 25 (3): 309–324. Bibcode:1963AnPhy..25..309H. doi:10.1016/0003-4916(63)90016-2. hdl:2027/mdp.39015095148113.
  • Hylleraas, Egil Andersen (1963). Resonance Method in Scattering Theory. Aerospace Research Laboratories, Office of Aerospace Research, United States Air Force; 21 pages{{cite book}}: CS1 maint: postscript (link)
  • Hylleraas, Egil A. (1964). The Schrödinger Two-Electron Atomic Problem. Advances in Quantum Chemistry. Vol. 1. pp. 1–33. doi:10.1016/S0065-3276(08)60373-1. ISBN 9780120348015.

See also

  • Two-electron atom
  • Hylleraas co-ordinates
  • Hylleraas configuration interaction (Hy-CI or H-CI)

Notes

  1. ↑ "Innehavere av Gunnerusmedaljen". Det Kongelige Norske Videnskabers Selskab. Archived from the original on May 21, 2012. Retrieved May 6, 2015.
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