A difluorine complex is a molecular complex involving a difluorine molecule (F2) and another molecule. The first example was gold heptafluoride (AuF7).[1] Instead of being a gold(VII) compound, AuF7 is an adduct of gold pentafluoride (AuF5) and F2. This conclusion has been repeatedly supported by calculations. Unlike dihydrogen complexes, which feature η2-H2, difluorine complexes feature "end-on" or η1-F2 ligand.[2]

See also

References

  1. ↑ Timakov, A. A.; Prusakov, V. N.; Drobyshevskii, Y. V. (1986). "Gold Heptafluoride". Doklady Akademii Nauk SSSR (in Russian). 291: 125–128.
  2. ↑ Conradie, Jeanet; Ghosh, Abhik (2019). "Theoretical Search for the Highest Valence States of the Coinage Metals: Roentgenium Heptafluoride May Exist". Inorganic Chemistry. 58 (13): 8735–8738. doi:10.1021/acs.inorgchem.9b01139. PMID 31203606.
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